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1 article(s) from Manicardi, Alex

Pyrene-modified PNAs: Stacking interactions and selective excimer emission in PNA₂DNA triplexes

Alex Manicardi,
Lucia Guidi,
Alice Ghidini and
Roberto Corradini

Beilstein J. Org. Chem. 2014, 10, 1495–1503, doi:10.3762/bjoc.10.154

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Figure 1: (a) TAT triplet structure showing Watson–Crick and Hoogsteen base pairing; the binding can be reinf...

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Scheme 1: Synthesis of the PNA monomer 1: i) 1. PPh₃, H₂O, THF; 2. TFA, 71%; ii) 1-pyreneacetic acid, HBTU, D...

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Figure 2: Fluorescence spectra at 347 nm excitation, recorded at 20 °C of: (a) PNA1, (b) PNA2, (c) PNA3, (d) ...

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Figure 3: (a) Increase in fluorescence intensity of the excimer band for PNA2 upon addition of complementary ...

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Figure 4: Ratio of the intensities of the pyrene excimer (F₄₇₄) and monomer emission (F₃₇₉) for the PNA probe...

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Published 02 Jul 2014

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Pyrene-modified PNAs: Stacking interactions and selective excimer emission in PNA2DNA triplexes

Pyrene-modified PNAs: Stacking interactions and selective excimer emission in PNA₂DNA triplexes